Yeah I wouldn't do food that's unpackaged. Too many variables with rotting stuff and whatnot. But furniture and electronics, you can just ride through a rich part of the area (Arlington, Virginia) and see piles and piles of shit just laying on the front lawns of some of the mansions out there and just grab a room full of stuff. My coffee table set was sitting infront of an embassy three years ago. Nice dark brown wood made of maple or something really heavy with a "Free" sign stuck to it. Now I got a nice coffee table and two end tables that probably cost a few hundred bucks.
If you say you won't take something that's free, then you were brought up in a rich family that pays hookers in gold while you dip your feet in your off-bedroom Jacuzzi while listening to Eminem cause you're gangster. Who the hell turns down free stuff? Had to break my wife of that cycle. Guy at the mall was handing out free cans of Red Bull as part of a promotion and she said no thanks. I had to bring her to the side and explain that even if she didn't want it, she never stopped to think I might have wanted a double fister and made her go back and second-thought the guy a can.
Free Cycle and Craigslist are good places to check. Haven't had any problems with them but heard stories of people getting robbed or lured in to scams or the owner suddenly changing their mind and asking for money anyways.
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