You can manually add a static route towards your 192.168.1.x network on your main pc. Disable any filetring or firewall on your router and find out which 10.0.0.x address it gets, fire up a comand prompt and write
Code:
route -p add 192.168.1.0 mask 255.255.255.0 10.0.0.(router ip)
-p means it is a permanent route. Now your main pc should be able to ping any other behind the router.
You might need to quit homegroup on your main pc (even if you never joined one) and enable the advanced files and printers sharing.
An alternative is to disable dhcp on your router and plug the network cable from the modem in a LAN port instead of WAN, leaving the modem dhcp assigning addresses and your router just being a bridge between wireless and wired networks. Every client will the have a 10.0.0.x address and you will be able to create an homegroup.