Off camera doesn't necessarily mean you have to use triggers - you can still trigger using optical slaves or even sync cords. The Cactus are nice, and they're very cheap. I use Alien Bee Cybersyncs for simple triggering purposes, but I keep a set of Cactus that has one trigger and 2 receivers as a backup to my Cybersyncs if I ever need it, and to loan out to friends. If you want to shoot high speed sync, bear in mind that forcing the flash to go faster duration than the recommended sync speed will weaken its power (certain strobes can bypass this, but not any hotshoe flashes, afaik), and you'll need to either increase your ISO to compensate, or bring your flash closer to your subject.
When you're looking for a flash, and if you're going to be shooting it exclusively off camera, you can look at the more powerful stuff like Norman 200Bs (can be found on Ebay) which come in 200WS and 400WS configurations. Get the set with the battery, and it'll teach you a lot about off camera lighting, especially about positioning and distance of flash to subject.
On camera, look for a flash head that can swivel - you don't want something that's fixed or has limited bounce applications. You want to be able to swivel the head at least left/right/up/down 180 degrees or so. The Yongnuos look like they fit the bill, I've never used those, however. Can always look into the Metz and Sigma line of flashes too, I've a buddy who swears by his Metz Mecablitz 50 in how well it stacks up to his 580.
There are also offerings by Sunpak - the 120J is pretty beefy for a flash, and it's pretty portable. If you want to do strobes, Alien Bees, Elinchrom DLite, Calument Genesis 300B, Interfit all make decent starter strobes that won't break the bank. I still use a set of old school Speedotron Black Line strobes, and they work great, as well as my new Dynalites for location work now. :D
It'll become a VERY slippery slope soon enough - pretty soon, you're going to start worrying less about gear, and more about light, and just how much of it you have.
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