As water vapour is directly related to temperature, it's also a positive feedback - in fact, the largest positive feedback in the climate system (
Soden 2005). As temperature rises, evaporation increases and more water vapour accumulates in the atmosphere. As a greenhouse gas, the water absorbs more heat, further warming the air and causing more evaporation. When CO2 is added to the atmosphere, as a greenhouse gas it has a warming effect. This causes more water to evaporate and warm the air to a higher, stabilized level. So the warming from CO2 has an amplified effect.